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  Advantages in Performance Duplex Stainless Steel  
 

There is no such thing as an all-purpose material for corrosion resistance, just as there is not just one corrosion type. Duplex alloys are in a class with several other materials for various types of corrosion resistance. Some of the corrosive environments listed below depict these differences. There are many more types of corrosive conditions but these are some for which stainless and nickel alloys are suitable.

Environment

Problem

Poor

Good

Best

Chlorides

Pitting, crevice corrosion

300 Series SS

Duplex alloys 317LXN®

Alloy 276 AL6XN®

Chlorides/Halides

Stress corrosion cracking

300 Series SS

Duplex alloys

Alloy 600/625 AL6XN®

Hydrochloric Acid

Pitting, crevice corrosion

Titanium, Duplex, 20 Cb-3

Alloy 22, 276

Zirconium, Tantalum

Hydrofluoric Acid

Pitting, crevice corrosion

Duplex Alloys

Silver, Gold

Copper, Alloy 400

Sulfuric Acid

Pitting, crevice corrosion

Copper-Nickel (MONEL®) Alloy 601

20 Cb-3

Alloy 622 HASTELLOY® C-22

General Acidic Attack

Critical Pitting

300 Series SS

317LNMo Duplex Alloys

Alloy 25-6 Mo Alloy 625

® AL6XN and 317LXN are Trademarks of Allegheny Ludlum Steel. ® MONEL and HASTELLOY are trademarks of Allegheny Ludlum Steel. ® Nitronic is a trademark of U.S. Steel.

As the table shows, some alloys outperform duplex alloys in many environments. Duplex is better than the 300 series in nearly every category. The consideration in the case of chlorides and halides must include costs.

Duplex alloys are nearly equal in strength to the C276 and AL6XN alloys. The pitting and crevice corrosion resistance of C276 and AL6XN are only slightly superior to the duplex alloys'. The corrosion rate for duplex is 23 mil/year; AL6XN is 17 mil/year. (Boiling NaOH, 290 degrees F for 48 hours.) Duplex alloys are much more readily available than higher-nickel alloys.

The elements that provide the strength and corrosion resistance in duplex are much more common than those found in some high-nickel alloys. For instance C276 contains tungsten. Carpenter 20Cb contains columbium and tantalum. The 625 alloy contains columbium, tantalum, cobalt, and titanium. Chromium, nickel, molybdenum, and nitrogen are common elements that provide the strength and corrosion resistance in the duplex alloys. The nitrogen is used in much the same way as it is used to protect the surface of Nitronic® 30.

 

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